Fabrication of 3D carbon microelectrodes for Li-Ion battery applications
نویسنده
چکیده
The fabrication of very high-aspect ratio 3D carbon microelectrodes for Li-Ion batteries is presented. Using a pyrolysis process under inert conditions, thick layers of patterned SU-8 photoresist (up to 600 μm in height) are converted into carbon. The micro-structures resulting from this process are used as anode for a Li-Ion battery. A detailed explanation on how to create SU-8 structures of aspect ratios as high as 15:1 using UV light is provided. New shapes that are more mechanically stable during the pyrolysis shrinkage are introduced. Some insight into how to create these structures on top of copper foil used as a current collector is provided as well.
منابع مشابه
Fabrication of single-layer MS2 (M=Mo, W) nanosheets using Li battery setup
Lithium intercalation is a convenient method to prepare few-layer and single-layer MS2 (M=Mo, W) nanosheets. This method is, however, very time-consuming (few days) and it is difficult to control the reaction parameters. To overcome these drawbacks, we have proposed a method to use an Li battery set-up to significantly reduce the reaction time (few hours) and electrochemically intercalate lithi...
متن کاملSnO2 Nanowires on Carbon Nanotube Film as a High Performance Anode Material for Flexible Li-ion Batteries
Today, Li-ion batteries (LIBs) are the most common rechargeable batteries used in electronic devices. SnO2 with theoretical specific capacity of 782 mAh/g is among the best anode materials for LIBs. In this report, Three-dimensional SnO2 nanowires (NWs) on carbon nanotube (CNT) thin film (SnO2 / CNT) is fabricated using a combination of vacuum filtration and thermal evaporation techniques. The ...
متن کاملA high performance lithium-ion battery using LiNa0.02K0.01FePO4/C as cathode material and anatase TiO2 nanotube arrays as anode material
In this paper we report on a lithium ion battery (LIB) based on improved olivine lithium iron phosphate/carbon (LiFePO4/C) as cathode material and LiNa0.02K0.01FePO4/C synthesized by sol-gel method and TiO2 nanotube arrays (TNAs) with an anatase phasesynthesized through anodization of Ti foil as an anode electrode. Crystallographic structure and surface morphology of the cathode and anode mate...
متن کاملElectrochemical Characterization of Low-Cost Lithium-Iron Orthosilicate Samples as Cathode Materials of Lithium-Ion Battery
Lithium-iron-orthosilicate is one of the most promising cathode materials for Li-ion batteries due to its safety, environmental brightness and potentially low cost. In order to produce a low cost cathode material, Li2FeSiO4/C samples are synthesized via sol-gel (SG; one sample) and solid state (SS; two samples with different carbon content), starting from Fe (III) in the raw materials (lo...
متن کاملTheoretical Assessment of the First Cycle Transition, Structural Stability and Electrochemical Properties of Li2FeSiO4 as a Cathode Material for Li-ion Battery
Lithium iron orthosilicate (Li2FeSiO4) with Pmn21 space group is theoritically investigated as a chathode material of Li-ion batteries using density functional theory (DFT) calculations. PBE-GGA (+USIC), WC-GGA, L(S)DA (+USIC) and mBJ+LDA(GGA) methods under spin-polarization ferromagnetic (FM) and anti-ferromagnetic (AFM) procedure are used to investigate the material properties, includin...
متن کامل